Amanda Jones

Amanda Jones

Contact Info

Dr. Amanda Jones

Associate Professor

A.B., 2001,  Princeton University (Prof. Maitland Jones, Jr.)
Ph.D., 2007,  University of Wisconsin-Madison (Prof. Hans J. Reich)
NIH Post-doctoral  Fellow, 2007-2010, California Institute of Technology (Prof. Brian M. Stoltz),

Office:Wake Downtown, Rm. 3816
Phone: (336) 702-1958
Email: jonesac@wfu.edu
Home Page: http://college.wfu.edu/sites/amanda-jones/

Research Description

Description of Research
Homogeneous gold(I) catalysts have emerged as powerful reagents for activating unsaturated hydrocarbons (pi-systems) toward nucleophilic addition and involvement in selective skeletal rearrangements. The products of these reactions are important building blocks in syntheses of pharmaceuticals and materials; however, the mechanisms of these processes are not fully understood.  Our work is focused on the examination of the structure, formation, and reactivity of gold complexes.  This includes a detailed exploration of ligand effects on the kinetics and stability of reactive intermediates relevant to catalysis.  The information we obtain will be used to improve the scope, catalytic efficiency, and cost-effectiveness of gold(I) catalysts, thus expanding chemists synthetic capabilities.

 

Publications

2015

  1. Jones, A. C. Gold p-Complexes as Model Intermediates in Gold Catalysis. Topics Curr. Chem. 2015, 357, 133–166.

2013–2014

  1. Sriram, M.; Zhu, Y.; Camp, A. M.;* Day, C. S.; Jones, A. C. Structure and Dynamic Behavior of Phosphine Gold(I)-Coordinated Enamines: Characterization of α-Metalated Iminium Ions. Organometallics, 2014, 33, 4157–4164.

Invited to be highlighted with a Cover Illustration.

  1. Jones, A. C.; May, J. A., Sarpong, R.; Stoltz, B. M. To a Symphony of Reactivity. Cascades Involving Catalysis and Sigmatropic Rearrangements. Angew. Chem. Int. Ed. 2013, 53, 2556–2591.
  2. Jones, A. C. Spectroscopic Advances in Organolithium Reactivity: The Contribution of Rapid-Injection NMR. Chapter in Lithium Compounds in Organic Synthesis, editors Renzo Luisi and Vito Capriati, Wiley-VCH, 2014. (Invited Book Chapter)
  3. Zhu, Y.; Day, C. S.; Zhang, L.; Hauser, K.;* Jones, A. C.       A Unique Au-Ag-Au Triangular Motif in a Trimetallic Halonium Dication: Silver Incorporation in a Gold(I) Catalyst. Chem. Eur. J. 2013, 19, 12264–12271.

Invited to be highlighted with a Frontispiece Image.

2010–2012

  1. Zhu, Y.; Day, Cynthia S.; Jones, A. C. Synthesis and Structure of Cationic Phosphine Gold (I) Enol Ether Complexes. Organometallics 2012, 31, 7332–7335.

Organometallics Journal ImageGold Rush with Silver Journal

 

 

 

 

 

 

 

 

Awards & Accomplishments

NSF Career Award, 2014-2019